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Container fire on deck: Cool burning transport units and nearby cargo exposed to the fire with copious quantities of water.

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Flammable liquid which has flashpoint of more than 35°C may be exempted from provisions of IMDG Code if it does not sustain combustion. The criteria for a liquid to be not sustaining combustion is if;

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While filling flammable liquid into packages the filler must ensure to take measures to prevent dangerous electrostatic discharge and must strictly adhere to the degree of filling for tanks.

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Vaporized flammable liquid may result in devastating Vapour Cloud Explosion. Some of the flammable liquids are corrosive to skin or to ships hull. Long term toxic effects are not classified and labelled hence ships personnel must take great care while dealing with spillage or fire involving flammable liquid. It is highly recommended to use self-contained breathing apparatus while dealing with flammable liquid incidents and accidents on board vessel.

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Liquids, or mixtures of liquids, or liquids containing solids in solution or suspension which gives off a flammable vapour at or below 60°C closed-cup test is classified as flammable liquid in transport regulations. Flashpoint is the lowest temperature of the liquid at which its vapour forms an ignitable mixture with air.

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Container fire under deck: Stop ventilation and close hatches. Use cargo space fixed fire-extinguishing system. If this is not available, create water spray using copious quantities of water.

2. substances transported or offered for transport at elevated temperatures in a liquid state, which give off a flammable vapour at temperatures equal to or below the maximum transport temperature.

Certain flammable liquids will float on water and if firefighting personnel direct the water jet on to the liquid it may result in spreading of fire further creating greater danger. During fire heated flammable liquid will release vapours which will burn with explosive effect. Firefighting personnel must stay in well protected area and use water spray to cool down the temperature of the liquid and vapour.

Certain flammable liquid which are viscous, such as paints, enamels, varnishes, adhesives and polishes, having a flashpoint of less than 23°C may be placed in packing group III provided it meets the conditions laid down in part III, chapter 32.3, of the United Nations Manual of Tests and Criteria, which includes:

Class 3 also includes liquid desensitized explosives which are explosive substances dissolved or suspended in water or other liquid substances, to form a homogeneous liquid mixture to suppress their explosive properties. Follwing are the entries in IMDG Code for liquid desentisized explosives:

Flammable liquid may have additional risk of toxicity or corrrosivity. For those liquids, having multiple hazards and are not listed by name in IMDG Code the shipper must classify them according to part 2.0 & 2.3 of the Code taking great attention to precedence of hazards, Classification of substances, mixtures and solutions with multiple hazards.

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For carriage on board ships flammable liquids are permited to be loaded on or under deck as per the stowage category assigned in IMDG Code for a particular UN Number with the assigned packing group and as per Document of compliance for ships carrying dangerous goods under the provisions of regulation II-2/19 of the 1974 SOLAS Convention, as amended.

Example: Benzoic Acid Molten has a flashpoint of 121 Deg C and its melting point is 122 Deg C, When transported as Molten the cargo temperature is greater than 122 Deg C which is higher than its flashpoint.

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(B) All employees shall be instructed that warning signs indicate a potentially hazardous situation that could result in death or serious injury. (3) Caution ...