Oxidising symbol

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FlammableSign

Corrosive solids, such as sodium hydroxide and phenol, can cause burns to the skin and eyes. Dust from corrosive solids can be inhaled and cause irritation or burns to the respiratory tract. Many corrosive solids, such as potassium hydroxide and sodium hydroxide, can produce considerable heat when dissolved in water.

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Corrosivechemicals

Corrosive gases and vapors are hazardous to all parts of the body; certain organs (e.g. the eyes and the respiratory tract) are particularly sensitive. The magnitude of the effect is related to the solubility of the material in the body fluids. Highly soluble gases (e.g. ammonia, hydrogen chloride) cause severe nose and throat irritation, while substances of lower solubility (e.g. nitrogen dioxide, phosgene, sulfur dioxide) can penetrate deep into the lungs.

Organic acids such as acetic acid should be stored separately from mineral acids.  While it is always best to segregate, acetic acid can be stored other flammable liquids.

Corrosive signmeaning

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Corrosivehazard

Two way traffic ahead. You are leaving a separated one-way roadway and entering a two-way roadway. Also used to remind drivers they are on a two-way road.

Corrosive liquids (e.g. mineral acids, alkali solutions and some oxidizers) represent a very significant hazard because skin or eye contact can readily occur from splashes and their effect on human tissue generally takes place very rapidly. Bromine, sodium hydroxide, sulfuric acid and hydrogen peroxide are examples of highly corrosive liquids. See Chemical-Specfic Protocols for specific corrosive liquids such as Hydrofluoric Acid and Phenol.

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Corrosivesubstance example

Picric acid can form explosive salts with many metals, or by itself when dry.  It is incompatible with other storage groups and should be stored seperately.  Perchloric acid is an extremely powerful oxidizer and must be kept away from all organic materials.  It should also be stored seperately.

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Explosivesign

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Many chemicals commonly used in the laboratory are corrosive or irritating to body tissue. They present a hazard to the eyes and skin by direct contact, to the respiratory tract by inhalation or to the gastrointestinal system by ingestion. Anecdotes offers incidents involving chemical burns from incorrectly handling corrosives.

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Mineral acids, including phosphoric, hydrochloric, nitric, sulfuric, and perchloric acid can be stored in a cabinet designed for corrosive acids.  Nitric acid can also be stored with oxidizers.  These non-metallic cabinets have no internal metallic parts, acid resistant coating and a cabinet floor constructed to be able to contain spillage. Volatile acids, such as oleum or fuming nitric acid, should be stored either in an acid cabinet or in a vented cabinet, such as the fume hood base, particularly after they have been opened.  Concentrated mineral acids can be very reactive, even with each other.