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While it’s unadvisable, if you do need to store mixed classes of dangerous goods in a common dangerous goods store, the different classes of dangerous must be separated by specific distances. These segregation distances are predetermined by the Australian Standard AS 3833-2008 - The storage and handling of mixed classes of dangerous goods.

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An oxidising agent has the potential to contribute to the combustion of other materials. While not necessarily combustible within themselves, these substances may cause or contribute to the combustion of other materials due to their ability to yield oxygen. These substances are also harmful to human health, so the appropriate personal protective equipment must be used. Oxidising substances must not make contact with the skin or eyes, and great care should be taken to avoid the inhalation of vapours or dusts from oxidising agents.

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Substances that will react dangerously are those substances that react in a manner that directly creates a hazard due to the reaction:

Oxidising agents can contribute to the combustion of other materials, with these chemicals also negatively affecting human health.

Before storing two different oxidising substances together, it’s crucial that you check the safety data sheets for each substance to determine their compatibility. If these substances are incompatible, they must be kept apart by at least 3 metres. If the two different substances will react dangerously, they must be segregated by at least 5 metres.

Oxidising agents can yield oxygen through a chemical reaction. This can create a fire risk when both oxygen and a flammable fuel are mixed in the presence of an ignition source. In addition to the segregation requirements for oxidizing substances, the isolation of ignition sources and flammable materials is a necessary precaution for workplaces who use, generate, handle or store these Class 5.1 chemicals.

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Joining the team as a Dangerous Goods Storage Consultant, Melissa Hampton became Storemasta's Marketing Manager in late 2021. With extensive knowledge and experience in chemical compliance, Melissa is responsible for leading the Marketing team and helping shape their marketing strategy. In her spare time, you can find Melissa hiking, swimming and enjoying the great outdoors in beautiful north-west Tasmania.

The chemicals that are incompatible with oxidising agents are those substances that fall under the dangerous goods classes outlined below:

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Oxidising agents are incompatible with many classes of dangerous goods – and may even be incompatible or react with chemicals within their own class. To avoid violent chemical reactions that could harm the people and property of your organisation, it’s vital that you have a disciplined approach to storing mixed classes of dangerous goods. If you’d like a Dangerous Goods Segregation Chart to help you identify which classes of dangerous goods are incompatible with oxidizing agents, you can access your own copy for FREE today.

If your onsite substances fall under the dangerous goods classes outlined above, they can only be stored in a common storage facility with oxidizing substances if they’re separated by at least 5 metres. In addition to this requirement, the dangerous goods classes must be kept in different compounds with separate spill containment sumps.

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To ensure that you do not pose any further risk to the people or property of your organisation, it’s important that you check the compatibility of oxidising agents and non-flammable non-toxic gases before they are stored together.

Substances that are classified as either toxic, dangerous when wet or corrosive will not react dangerously with oxidising agents, but there is the possibility that they will pose further risks upon the people and property of your organisation if they are mixed. Storing these incompatible substances in a dangerous goods store containing oxidising agents must be avoided— at all times.

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Generally speaking, Class 2.2 Non-Flammable Non-Toxic gases are compatible with most other classes of dangerous goods. However, some non-flammable non-toxic gases are incompatible with oxidising agents.

If these substances are incompatible, they must be kept apart by at least 3 metres. The compatibility of these substances can be determined by consulting the safety data sheet for each substance.

Some substances that share the same dangerous goods classification may be compatible with each other. This means that some classes of dangerous goods may be stored within the same store safely.

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We’ll look at these requirements in depth below, so you can understand the dangers associated with your oxidising agent – and what you can do to minimise risk. But first, let’s look at the difference between incompatible substances and those that can react dangerously.

The segregation of incompatible classes of dangerous goods can be achieved by using separate chemical storage cabinets or outdoor dangerous goods stores.

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The storage and segregation of oxidising agents in the workplace may include the use of indoor Class 5.1 safety cabinets.

Oxidizing substances are a class of dangerous goods that requires careful chemical segregation practices. This is because these chemicals pose a severe risk, due to the various classes of dangerous goods that they can react dangerously with – or are incompatible with.

To protect staff and property, oxidising substances must be segregated from dangerous goods that are incompatible and those that react dangerously.

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Some oxidising agents are incompatible with other Class 5.1 chemicals, with some substances even reacting dangerously if they’re kept or handled in the same area.

To determine the segregation rules for oxidizing substances, you can refer to the Australian Standard AS/NZS 3833 – The storage and handling of mixed classes of dangerous goods, in packages and intermediate bulk containers.

If oxidising agents must be stored with other incompatible substances in the same dangerous goods store, you are required to keep these incompatible substances apart by a distance of at least 3 metres.

IMPORTANT: If you’d like to learn more about the safe storage of oxidising agents, check out our blog that details the Ventilation Requirements for Oxidising Agent Storage Cabinets.

The required separation distance for oxidising agents from other incompatible dangerous goods depends on the compatibility of the chemicals.

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If your workplace uses oxidising agents, such as hydrogen peroxide and potassium nitrate, it’s very important that you store and manage these substances in a way that reduces the risk that they pose to the people and property of your organisation. One key factor to consider when storing an oxidising agent, is to ensure that the chemical is kept well away from other incompatible classes of dangerous goods. There are many chemicals that are incompatible with oxidising substances — and there are other chemicals that will react dangerously with oxidisers.