Materials other than pyrophoric materials that can react with air and without energy added. These will only ignite in large quantities or after long periods of time.

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The GHS classification further divides health and physical hazards into separate classes such as toxicity, irritation, sensitization, flammability, etc. The severity of the hazard within each class is described by the category. Some classes have five categories; other classes have only one category. Category 1 or A always represents the highest hazard within that class. The higher the category number, the lower the hazard. The classes, their categories and pictograms are as follows:

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In compliance with the new Hazard Communication Standard, SDS are divided into 16 sections and are required to provide the following information:

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The identified hazards have to be communicated on the container label and in documents called Safety Data Sheets (SDS). Manufacturers and distributors are required to provide safety data sheets to their clients that describe the results of the classification and all known hazards of a chemical.

The main health and physical hazards have to be indicated on the product label by using pictograms, signal words, and standardized hazard statements. The pictograms are explained in the next paragraph. The signal word "Danger" is used for severe hazards and "Warning" is used for less severe hazards. Based on the classification of the product, the hazards are described in standardized phrases called "hazard statements". For example, a highly toxic chemical requires a statement "Fatal if inhaled or swallowed".

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The image below shows the pictograms used for labeling. Underneath each pictogram is a list with classes the pictogram is used for.

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OSHA 1910.1200 Hazard Communication Standard:http://www.osha.gov/pls/oshaweb/owadisp.show_document?p_table=STANDARDS&p_id=10099

The Globally Harmonized System (GHS) was developed by the United Nations for international standardization of hazard classification and communication. OSHA has adopted GHS, and beginning June 2015, all manufacturers are required to prepare labels and SDS according to GHS. Some manufacturers already comply with this regulation.

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The Hazard Communication Standard (29CFR 1910.1200) requires all manufacturers or distributors of any products containing chemicals to evaluate the chemical hazards of the product. The evaluation is performed by classifying each chemical based on published toxicological or other data to determine its physical and health hazards.

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Besides electronic access it is highly recommended to have hardcopies of highly toxic and corrosive chemicals available in the laboratory so they can be taken to the hospital if an exposure occurs.

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SDS can be available as electronic version or as hardcopies. A computer with internet connection is particularly useful to quickly access the latest SDS. Webpages like Sigma-Aldrich or Fisher Scientific are convenient and reliable sources for finding SDS. If no internet access is available, SDS of the most hazardous, largest volume, and most frequently used materials should either be stored on a computer accessible to everybody working in the lab, or as hardcopies in a binder.

Safety Data Sheets (SDS), formerly called Material Safety Data Sheets (MSDS), communicate the hazards associated with using chemicals. They are an important source of information for workers, lab personnel, emergency responders, and emergency medical personnel. As they often provide very limited information on safe handling procedures, they should be used in conjunction with safety guides provided by DRS and other knowledgeable sources (Prudent Practices, eEROS, textbooks, etc.) and standard operating procedures written for your group.

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Division of Research Safety 102 Environmental Health and Safety Building101 South Gregory Street, MC-225 (217) 333-2755 drs@illinois.edu

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